Web[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the... WebJan 10, 2014 · Three 2D luminescent isomeric porous coordination polymers are synthesized and characterized. Their luminescence properties can be modified by grinding and they can act as mechanochromic materials and their properties are probably related to the weak interactions of cuprophilicity and π–π interactions. Supporting Information …
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WebMay 22, 2024 · Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.-C. Chen, Y.-C. Tsai, and co-workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain-like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their … WebJul 26, 2024 · DFT calculations suggest the ligand-unsupported cuprophilicity originate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal mol … immortals phoenix rising a crying shame
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WebApr 12, 2024 · PDF On Apr 12, 2024, Muhammad Asim published molecules-27-05951-v2 (2) Find, read and cite all the research you need on ResearchGate WebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported Cu I –Cu I interaction in two recently reported complexes Josep-M. Poblet and M. Bénard, … Webintertrimer cuprophilicity.14 The computed gross populations of HOMO and LUMO in the [Cu6(Pz)6] trimer dimer are listed in Table S6, while the contours of the frontier orbitals for the [Cu6 (Pz)6] with single-crystal geometry is shown in Figs. 1g and 1h. immortals phoenix rising big lyre